Vibration-rotational Spectroscopy and Molecular Dynamics

Vibration-rotational Spectroscopy and Molecular Dynamics
Author :
Publisher : World Scientific
Total Pages : 578
Release :
ISBN-10 : 9810216351
ISBN-13 : 9789810216351
Rating : 4/5 (51 Downloads)

Book Synopsis Vibration-rotational Spectroscopy and Molecular Dynamics by : Du?an Papou?ek

Download or read book Vibration-rotational Spectroscopy and Molecular Dynamics written by Du?an Papou?ek and published by World Scientific. This book was released on 1997 with total page 578 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book reviews the results of vibration-rotational spectroscopy of molecules obtained recently by combining modern computational methods of quantum chemistry with the new techniques of high-resolution rotational and vibration-rotational spectroscopy. It shows for example that the tunneling vibration-rotational spectroscopy of the van der Waals complexes provides a new look at intermolecular forces while the high precision and sensitivity of the submillimeter-wave and Fourier transform microwave spectroscopy make it possible to study complex rotational spectra of molecules in excited vibrational states. New results of high level ab initio quantum chemical computations of vibrational and rotational energy levels and dipole moment functions of unusual molecules will be discussed together with the recent discovery of clustering of energy levels in asymmetric tops. Group theoretical analysis of floppy molecules, especially the tunneling effects in nonrigid molecules, will also be discussed.


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